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Suddenly unable to send emails

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Thunderbird can receive emails but I cannot send them. I get the error message per the screenshot below concerning SMTP.

I have a MacBook Air with Mac OS Sequoia 15.7.2. The error started yesterday (21 November). Just finished conversing with Optus support and they say that it's not at their end: webmail works okay, can receive email and send it (will note there was a brief hiccough earlier today when could not send from webmail, but okay now). All settings as recommended (port for incoming server actually different from what Optus recommends, but when I changed it from 995 to 110, Thunderbird stopped being able to download emails, so changed it back again. Port for outgoing is as recommended, 25.) I tried lowering security, as suggested by Thunderbird help list, and no change so restored it.

I have the latest version of Thunderbird for Mac, 145.0.

My partner, who also uses Thunderbird, cannot receive emails either. He has an older Mac running an older OS.

I have included two images, the second one showing details of selected server. When I clicked 'fetch certificate' it failed. Does that signify anything important?

The error console shows a lot of information, which of course I cannot understand, but can screenshot some of it if that would help.

No firewall, no virus protection, no VPN.

Any ideas as to what might be going on?

Thunderbird can receive emails but I cannot send them. I get the error message per the screenshot below concerning SMTP. I have a MacBook Air with Mac OS Sequoia 15.7.2. The error started yesterday (21 November). Just finished conversing with Optus support and they say that it's not at their end: webmail works okay, can receive email and send it (will note there was a brief hiccough earlier today when could not send from webmail, but okay now). All settings as recommended (port for incoming server actually different from what Optus recommends, but when I changed it from 995 to 110, Thunderbird stopped being able to download emails, so changed it back again. Port for outgoing is as recommended, 25.) I tried lowering security, as suggested by Thunderbird help list, and no change so restored it. I have the latest version of Thunderbird for Mac, 145.0. My partner, who also uses Thunderbird, cannot receive emails either. He has an older Mac running an older OS. I have included two images, the second one showing details of selected server. When I clicked 'fetch certificate' it failed. Does that signify anything important? The error console shows a lot of information, which of course I cannot understand, but can screenshot some of it if that would help. No firewall, no virus protection, no VPN. Any ideas as to what might be going on?
Attached screenshots

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